Granular Activated Carbon (GAC) Adsorption of Herbicide (Metsulfuron methyl) in Water and Doping Zn-TiO2 Activated Carbon Coupling with Batch Photocatalytic Oxidation

Original scientific paper

Journal of Sustainable Development of Natural Resources Management
ARTICLE IN PRESS (pending volume/issue assignment), 1010625
DOI: https://doi.org/10.13044/j.sdnarema.d1.0625 (registered soon)
Singto Sakulkhaemaruethai1 , Nathaporn Areerachakul2, Jaya Kandasamy3, Aran Kwanpan2, Saravanamuthu Vigneswaran3, Tien - Vinh Nguyen4, Thi Thu Trang Nguyen5, Do Van Manh5
1 Rajamangala University of Technology Thanyaburi, Pathum Thani, Thailand
2 Suan Sunandha Rajabhat University, Bangkok, Thailand
3 University of Technology Sydney, Sydney, Australia
4 University of Technology, Sydney, Sydney, Australia
5 The Vietnam Academy of Science and Technology, Hanoi, Vietnam

Abstract

The granular activated carbon (GAC) filter was found to be very effective as a treatment for the removal of herbicide. The Sips isotherms showed the best fit with 6.6% error. Fixed bed column experiments packed with GAC were conducted with different GAC bed heights (5, 10 and 15 cm) and different effluent velocities. The GAC fixed bed column show the model simulation fits reasonably well during the initial period and also with a shallow bed depth (5 cm) with flow rate 4 m/h.  Another set of experiment is GAC and GAC doping Zn with various concentrations to remove herbicide from water. The doped Zn – Tio2 GAC batch experiments can remove MM in term of DOC from 60 to 77% by using different w/v of doped Zn onto TiO2 – GAC. The highest remove of MM 77% by using batch experiment was 0.125% w/v Zn -TiO2.

Keywords: Herbicide, Granular activated carbon, Adsorption, Sips, Fixed bed, Doped Zn-GAC.

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